4.6 Article

Electrochemical reduction of graphene oxide in organic solvents

Journal

ELECTROCHIMICA ACTA
Volume 56, Issue 15, Pages 5363-5368

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2011.03.117

Keywords

Graphene; Graphite; Reduction; Electrochemistry; Electrochemical double layer capacitor

Funding

  1. Grants-in-Aid for Scientific Research [22550198] Funding Source: KAKEN

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Graphene oxide (GO) cast on conductive substrates was electrochemically reduced in some organic solvents. The amount of electricity required for the almost complete reduction of GO was 2.0C for 1 mg GO, corresponding to attaching of a one-electron reducible species to each benzene ring in graphene. The electrochemically reduced GO film gave an electrical conductivity of about 3 S cm(-1) and exhibited a relatively high specific capacitance of 147.2 F g(-1) in propylene carbonate. The electrochemical reduction of GO was feasible on Al foils as well. (C) 2011 Elsevier Ltd. All rights reserved.

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