Journal
ELECTROCHIMICA ACTA
Volume 57, Issue -, Pages 220-227Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2011.08.056
Keywords
Ionic liquids; DSC; Annealing
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The phase transitions in ionic liquids (ILs) of the N-alkyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR1ATFSI) family show a common pattern, which implies a typical and characteristic crystal packing. Many of these features are also observed for the N-alkyl-N-methylpiperidinium bis(trifluoromethanesulfonyl)imide (PIP1ATFSI) family. Here we report the thermal behavior of some ILs of the PYR1ATFSI and PIP1ATFSI families and a few others having different anions. The thermal history was found to decide which phases will appear and, therefore, specific protocols were defined to obtain the desired phases in a reasonable amount of time. (C) 2011 Elsevier Ltd. All rights reserved.
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