Journal
ELECTROCHIMICA ACTA
Volume 55, Issue 16, Pages 4805-4811Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2010.03.048
Keywords
Co3O4 nanoplatelets; Porous; Self-supported formation; Textural characteristics; Electrochemical properties
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Funding
- Foundation for Excellent Middle-aged or Young Scientists from Shandong Province [BS2009CL029]
- Australian Research Council [DP0879070]
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In this paper, we have reported a simple and rapid approach for the large-scale synthesis of beta-Co(OH)(2) nanoplatelets via the microwave hydrothermal process using potassium hydroxide as mineralizer at 140 degrees C for 3 h. Calcining the beta-Co(OH)(2) nanoplatelets at 350 degrees C for 2 h, porous Co3O4 nanoplatelets with a 3D quasi-single-crystal framework were obtained. The process of converting the beta-Co(OH)(2) nanoplatelets into the Co3O4 nanoplatelets is a self-supported topotactic transformation, which is easily controlled by varying the calcining temperature. The textural characteristics of Co3O4 products have strong positive effects on their electrochemical properties as electrode materials in lithium-ion batteries. The obtained porous Co3O4 nanoplatelets exhibit a low initial irreversible loss (18.1%). ultrahigh capacity, and excellent cyclability. For example, a reversible capacity of 900 mAh g(-1) can be maintained after 100 cycles. (C) 2010 Elsevier Ltd. All rights reserved.
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