4.6 Article Proceedings Paper

New type of imidazole based salts designed specifically for lithium ion batteries

Journal

ELECTROCHIMICA ACTA
Volume 55, Issue 4, Pages 1450-1454

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2009.05.008

Keywords

Lithium ion; Batteries; Salts; Electrolytes; Synthesis

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In this manuscript we announce new type of tailored imidazole-derived salts designed. synthesized and tested for application in lithium conductive electrolytes. Basic characterization of the structure of described materials has been made by Raman, IR and NMR ((13)C NMR, (19)F NMR) techniques. DSC and CV studies showed thermal stability of all salts over 200 degrees C and electrochemical stability in liquid and solid polymer solvents up to +4.6 V vs. metallic lithium anode and Al collectors. Such properties proved applicability of these salts as lithium electrolytes for modern types of lithium ion batteries. (C) 2009 Elsevier Ltd. All rights reserved.

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