Journal
ELECTROCHIMICA ACTA
Volume 55, Issue 15, Pages 4495-4500Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2010.02.092
Keywords
Electrosynthesis; Arylpyridazines; Catalyzed; Nickel-2,2 '-bipyridine complexes; Cyclic voltammetry
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Funding
- Universite Paris Est Creteil Val de Marne (UPEC)
- ANR
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The nickel-2,2'-bipyridine catalyzed electrochemical cross-coupling reaction between an aryl halide and a chloropyridazine was investigated by an electrochemical study The electrochemical behavior of the divalent nickel complex is affected by the presence of pyridazine rings which act as co-ligands of nickel Cyclic voltammetry indicates that the cross-coupling reaction involves first a rapid oxidative addition of the chloropyridazine on the electrogenerated zerovalent nickel complex. The coupling product is then obtained by reaction with the aryl halide. (C) 2010 Elsevier Ltd. All rights reserved.
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