Journal
ELECTROCHIMICA ACTA
Volume 54, Issue 24, Pages 5605-5613Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2009.05.017
Keywords
Redox shuttle; Overcharge protection; Lithium-ion battery; Electrolyte additive
Categories
Funding
- U.S. Department of Energy
- Freedom-CAR and Vehicle Technologies Office
- Argonne National Laboratory is operated for the U.S. Department of Energy by UChicago Argonne, LLC [DE-AC0Z-06CH11357]
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Overcharge protection is not only critical for preventing the thermal runaway of lithium-ion batteries during operation, but also important for automatic capacity balancing during battery manufacturing and repair. A redox shuttle is an electrolyte additive that can be used as intrinsic overcharge protection mechanism to enhance the safety characteristics of lithium-ion batteries. The advances on stable redox shuttles are briefly reviewed. Fundamental studies for designing stable redox shuttles are also discussed. (C) 2009 Published by Elsevier Ltd.
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