Journal
ELECTROCHIMICA ACTA
Volume 54, Issue 4, Pages 1333-1338Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2008.09.008
Keywords
Electropolymerization; Polythiophene; Polypyrrole; Bipyrrole
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Funding
- Scientific and Technical Research Council of Turkey (TUBITAK)
- Turkish Academy of Sciences (TUBA)3
- Turkish State Planning Organization
- Middle East Technical University
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A novel conducting polymer was successfully synthesized via electropolymerization of 1-(1H-pyrrol-1-yl)-2,5-di(thiophen-2-yl)-1H-pyrrole. The electrochemical and electro-optical properties of the corresponding polymer, which was the first example of polymer containing 1,1'-bipyrrole units, were elaborated using electroanalytical and spectroscopic techniques. Cyclic voltammograms and electro-optical studies showed that the polymer has a stable and well-defined reversible redox process as well as electrochromic behavior. The processable polymer film also possessed a yellowish orange light emitter property. (C) 2008 Elsevier Ltd. All rights reserved.
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