Journal
ELECTROCHIMICA ACTA
Volume 54, Issue 27, Pages 7114-7120Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2009.07.021
Keywords
PtRu nanoparticles; Multiwalled carbon nanotubes (MWCNTs); 2-Aminophenoxazin-3-one (APZ); Electrocatalytic; Fuel cells
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Funding
- Natural Science Foundation of Guangxi Province [0728043]
- Guangxi Ministry of Education
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A new process to prepare well-dispersed PtRu nanoparticles on 2-aminophenoxazin-3-one (APZ)-functionalized multiwalled carbon nanotubes (PtRu/APZ-MWCNTs) was reported. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectrometry (FT-IR), UV-vis absorption spectra as well as Raman spectra were used for the catalyst characterization. The Raman spectroscopic results reveal that APZ-functionalized MWCNTs has good integrity and electronic structure than MWCNTs treated with chemical acid. The composite catalyst shows excellent electrocatalytic activity toward methanol oxidation and appears as a promising candidate for use in direct methanol fuel cells. Cyclic voltammetry and chronoamperometry studies indicate that the PtRu/APZ-MWCNTs catalysts exhibited higher electrochemical active surface area, electrocatalytic activity and stability for the electro-oxidation of methanol as compared to that of PtRu electrocatalysts supported on conventional acid-treated MWCNTs and carbon black. (C) 2009 Elsevier Ltd. All rights reserved.
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