Journal
ELECTROCHIMICA ACTA
Volume 53, Issue 20, Pages 6033-6037Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2008.02.106
Keywords
co-precipitation; hydroxide; LiNi0.5Mn0.5O2; positive electrode; lithium; battery
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Funding
- National IT Industry Promotion Agency (NIPA), Republic of Korea [C1090-0801-0029] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [과C6A1908] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Spherical (Ni0.5Mn0.5)(OH)(2) with different secondary particle size (3 mu m, 10 mu m in diameter) was synthesized by co-precipitation method. Mixture of the prepared hydroxide and lithium hydroxide was calcined at 950 degrees C for 20 h in air. X-ray diffraction patterns revealed that the prepared material had a typical layered structure with R (3) over barm space group. Spherical morphologies with mono-dispersed powders were observed by scanning electron microscopy. It was found that the layered Li[Ni0.5Mn0.5]O-2 delivered an initial discharge capacity of 148 mAh g(-1) (3.0-4.3 V)though the particle sizes were different. Li[Ni0.5Mn0.5]O-2 having smaller particle size (3 mu m) showed improved area specific impedance due to the reduced Li+ diffusion path, compared with that of Li[Ni0.5Mn0.5]O-2 possessing larger particle size (10 mu m). Although the Li[Ni0.5Mn0.5]O-2 (3 mu m) was electrochemically delithiated to Li-0.39[Ni0.5Mn0.5]O-2, the resulting exother. mic onset temperature was around 295 degrees C, of which the value is significantly higher than that of highly delithiated Li1-delta CoO2 (similar to 180 degrees C). (C) 2008 Published by Elsevier Ltd.
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