4.6 Article

Mesoporous Fe2O3 nanoparticles as high performance anode materials for lithium-ion batteries

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 29, Issue -, Pages 17-20

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2013.01.002

Keywords

Hematite; Nanoparticle; Mesoporous; Lithium-ion battery; Anode material

Funding

  1. 973 Program, China [2013CB934103]
  2. National Natural Science Foundation, China [21173054]
  3. Science & Technology Commission of Shanghai Municipality, China [08DZ2270500]

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This work introduces an effective, inexpensive, and large-scale production approach to the synthesis of Fe2O3 nanoparticles with a favorable configuration that 5 nm iron oxide domains in diameter assembled into a mesoporous network. The phase structure, morphology, and pore nature were characterized systematically. When used as anode materials for lithium-ion batteries, the mesoporous Fe2O3 nanoparticles exhibit excellent cycling performance (1009 mA h g(-1) at 100 mA g(-1) up to 230 cycles) and rate capability (reversible charging capacity of 420 mA h g(-1) at 1000 mA g(-1) during 230 cycles). This research suggests that the mesoporous Fe2O3 nanoparticles could be suitable as a high rate performance anode material for lithium-ion batteries. (c) 2013 Elsevier B.V. All rights reserved.

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