Journal
ELECTROCHEMISTRY COMMUNICATIONS
Volume 34, Issue -, Pages 348-350Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2013.07.009
Keywords
Supercapacitors; Nanoporous electrodes; Anomalous capacitance
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Funding
- Engineering and Physical Science Research Council [EP/H004319/1]
- Engineering and Physical Sciences Research Council [EP/H004319/1] Funding Source: researchfish
- EPSRC [EP/H004319/1] Funding Source: UKRI
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By means of Monte Carlo simulations we show that a pore-width dependent dielectric permittivity, epsilon(p)(L), may diminish the pore-size dependence of the surface-specific capacitance. This is different from the case of a fixed dielectric permittivity, epsilon(p) = const, which leads to an increase of capacitance when the pore width becomes comparable to the ions size. (C) 2013 Elsevier B.V. All rights reserved.
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