4.6 Article

Fabrication of favorable interface between sulfide solid electrolyte and Li metal electrode for bulk-type solid-state Li/S battery

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 22, Issue -, Pages 177-180

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2012.06.015

Keywords

Lithium metal secondary battery; All-solid-state battery; Li/S battery; Solid electrolyte; Interface

Funding

  1. Japan Science and Technology Agency (JST)
  2. Core Research for Evolutional Science and Technology (CREST) Project
  3. Japan Society for the Promotion of Science (JSPS)
  4. Grants-in-Aid for Scientific Research [21246098, 10J08610] Funding Source: KAKEN

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Formation of favorable interface between a lithium metal electrode and a solid electrolyte by inserting a lithium thin film contributes to reproducible lithium dissolution and deposition in rechargeable bulk-type all-solid-state cells. A lithium symmetrical cell with a Li2S-P2S5 solid electrolyte was galvanostatically cycled at room temperature. A bulk-type solid-state Li/S cell exhibited a good cycle performance with a capacity higher than 900 mAh g(-1) at 0.064 mA cm(-2) (0.03 C). (C) 2012 Elsevier B.V. All rights reserved.

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