4.6 Article

Highly ordered iron oxide nanotube arrays as electrodes for electrochemical energy storage

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 13, Issue 6, Pages 657-660

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2011.03.040

Keywords

Iron oxide; Anodization; Nanotube array; Supercapacitors

Funding

  1. Research Grants Council of the Hong Kong Special Administrative Region, China [PolyU5187/09E]
  2. Hong Kong Polytechnic University [A-PA6A, A-PK30]
  3. National Key Technology Research and Development Program of China [2007BAE12B01]

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Highly ordered alpha-Fe(2)O(3) nanotube arrays have been fabricated by a simple and cost-effective anodization method on iron foils. The alpha-Fe(2)O(3) nanotube arrays exhibit high specific capacitance (138 F.g(-1) at 1.3 A.g(-1)), remarkable rate capability (91 F.g(-1) at 12.8 A.g(-1)) and good cycling stability (the capacitance retention close to 89% after 500 cycles), clue to the unique nanostructures of the alpha-Fe(2)O(3) nanotube arrays, which providing high surface area, fast ion transport pathways and robust structures. These features made the alpha-Fe(2)O(3) nanotube array electrode very attractive for supercapacitor applications. (C) 2011 Elsevier B.V. All rights reserved.

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