4.6 Article

Vertically aligned silicon/carbon nanotube (VASCNT) arrays: Hierarchical anodes for lithium-ion battery

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 13, Issue 5, Pages 429-432

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2011.02.012

Keywords

Lithium-ion battery; Silicon; Anode; Carbon nanotubes; CVD

Funding

  1. US Department of Energy's Office of Vehicle Technologies [DE-AC02-05CHl1231]
  2. Ford Motor company
  3. National Science Foundation [CBET-0933141]
  4. Edward R. Weidlein Chair Professorship Funds
  5. Center for Complex Engineered Multifunctional Materials (CCEMM)

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Vertically aligned silicon/carbon nanotube arrays are directly synthesized on Inconel metal current collector as lithium-ion battery anode. The hierarchical anode eliminates the traditional preparation of electrodes obviating the use of polymer binder facilitating the desired lithium ion and electron kinetics in the electrode. The simple approach demonstrates a facile non-template way to prepare integrated anode architectures. The as synthesized anode demonstrates stable capacity similar to 2000 mAhg(-1) with only 6% irreversible loss observed in the first cycle. (C) 2011 Elsevier B.V. All rights reserved.

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