Electrocatalytic oxidation of formic acid on functional MWCNTs supported nanostructured Pd-Au catalyst

In this work, PdAu nanocatalysts with different weight ratio of Pd and Au supported on functional multi-walled carbon nanotubes (f-MWCNTs) were prepared, and their electrocatalytic activity for the oxidation of formic acid was also studied. The electrocatalysts were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The electrochemical results showed that the 4Pd1Au/f-MWCNTs (by weight) catalyst, exhibited distinctly higher activity and better stability in formic acid electrooxiclation than the Pd/f-MWCNTs catalyst. The Nano-Au improves potentially the performance of Pd-based electrocatalysts for the direct formic acid fuel cells (DFAFCs). (C) 2009 Elsevier B.V. All rights reserved.