4.6 Article

TiO2@Sn core-shell nanotubes for fast and high density Li-ion storage material

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 10, Issue 11, Pages 1669-1672

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2008.08.035

Keywords

TiO2@Sn core-shell; Nanotube; Li-ion cell; High density; Anode; Rate capability

Funding

  1. MKE/IITA [2008-F-019-01]
  2. Korea Science and Engineering Foundation (KOSEF)
  3. Korea government (MEST) [R01-2008-000-20142-0]
  4. National Research Foundation of Korea [R01-2008-000-20142-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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TiO2@Sn core-shell nanotube material prepared by thermal decomposition of SnCl4 on TiO2 nanotubes at 300 degrees C has been demonstrated superior Li-ion storage capability of 176 mA h/g even at high current rate of 4000 mA/g (charge and discharge of all TiO2 within 5 min) in spite of using low carbon content (5 wt%). This value corresponds to volumetric energy densities of 317 mA h/cm(3), and its value was 3.5-fold larger than that of the bare TiO2 nanotubes. (C) 2008 Elsevier B.V. All rights reserved.

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