Journal
ELECTROCHEMISTRY
Volume 81, Issue 5, Pages 353-355Publisher
ELECTROCHEMICAL SOC JAPAN
DOI: 10.5796/electrochemistry.81.353
Keywords
Anodic Alkoxylation; Carbon-Carbon Bond Forming Reactions; HFIP; Solid-Supported Bases
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Funding
- The Ministry of Education, Culture, Sports, Science and Technology, Japan [19685014, 23685036]
- The Kurata Memorial Hitachi Science and Technology Foundation
- Grants-in-Aid for Scientific Research [19685014, 23685036] Funding Source: KAKEN
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We have demonstrated anodic alkoxylation of lactams followed by reactions with carbon nucleophiles in a one-pot manner using 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) as a solvent. In the two-step transformation, HFIP acted as a nucleophile in the presence of solid-supported bases, while it acted as an inert solvent in the absence of solid-supported bases. This enabled us to conduct anodic alkoxylation of lactams and subsequent C-C bond forming reactions without replacing the solvent. (C) The Electrochemical Society of Japan, All rights reserved.
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