Journal
ELECTROCHEMISTRY
Volume 80, Issue 10, Pages 755-758Publisher
ELECTROCHEMICAL SOC JAPAN
DOI: 10.5796/electrochemistry.80.755
Keywords
Sodium-Ion Battery; Non-Aqueous Electrolyte; Ionic Liquid
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The electrochemical insertion and de-insertion of sodium ion in hard carbon has been monitored in electrolytes consisting of sodium perchlorate (NaClO4), propylene carbonate (PC), and an ionic liquid N,N-diethyl-N-methoxy-ethyl ammonium bis(trifluoromethane sulfonyl)imide (DEMETFSI). Voltammetric observation revealed that the reversible sodium insertion is inhibited by the content of DEMETFSI in the electrolyte. The reversible signs of sodium insertion become obvious when the volumetric content of DEMETFSI was 70%. The inhibition effect for sodium insertion by DEMETFSI is somewhat in relation to the change in coordination with sodium ion in electrolyte. (C) The Electrochemical Society of Japan, All rights reserved.
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