Journal
ELECTROCHEMISTRY
Volume 77, Issue 8, Pages 639-641Publisher
ELECTROCHEMICAL SOC JAPAN
DOI: 10.5796/electrochemistry.77.639
Keywords
Thermoelectromotive Force; Reaction Entropy; Metal Complex; Ionic Liquid
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan (MEXT) [17073016]
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Reaction entropies of some metal complex redox couples in an amide-type room-temperature ionic liquid. 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) have been estimated by Measuring the thermoelectromotive force at a non-isothermal cell. It is suggested that the reaction entropy is dependent on the difference in the charge densities of the oxidant and reductant of a redox couple, probably related to the coulombic interaction between the redox species and the ions composing the ionic liquid.
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