Journal
ELECTROCHEMISTRY
Volume 77, Issue 8, Pages 696-698Publisher
ELECTROCHEMICAL SOC JAPAN
DOI: 10.5796/electrochemistry.77.696
Keywords
Lithium-ion Battery; Ionic Liquid; Bis(fluorosulfonyl)imide
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Funding
- New Energy and Industrial Technology Development Organization (NEDO), Japan
- Ministry of Education, Culture Sports, Science and Technology of Japan (MEXT)
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The electrochemical behavior of a graphitized electrode was investigated in a room-temperature ionic liquid based on bis(fluorosulfonyl)imide (FSI-) with the addition of propylene carbonate (PC) or vinylene carbonate (VC). The reversible, significant lithium-ion (Li+) insertion/extraction was observed in the additive-free FSI-based ionic liquid, while the additive systems showed weak, reversible responses (VC) and degraded responses (PC). AC impedance measurements suggested that the presence of FSI- extremely reduces the electrode/electrolyte interface impedance, which allows Li+ to intercalate into a graphitized electrode reversibly. By contrast, the addition of VC inhibits the reversible Li+ intercalation in spite of FSI- existence.
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