4.2 Article

Meso-meso Linked Porphyrin Dimers for Dye-sensitized Solar Cells

Journal

ELECTROCHEMISTRY
Volume 77, Issue 3, Pages 206-209

Publisher

ELECTROCHEMICAL SOC JAPAN
DOI: 10.5796/electrochemistry.77.206

Keywords

Dye-sensitized Solar Cell; Porphyrin Array; Meso-meso Linked Dimer

Funding

  1. New Energy and Industrial Technology Development Organization (NEDO)
  2. Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan [18205022]
  3. Grants-in-Aid for Scientific Research [18205022] Funding Source: KAKEN

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Directly meso-meso linked porphyrin dimers were utilized as novel sensitizers of dye-sensitized solar cells. Three dimers were prepared: bis-freebase (FbP(1)-FbP(2)a), zinc-freebase (ZnP1-FbP(2)a), and bis-zinc (ZnP1-ZnP(2)a), which exhibited maximum energy conversion efficiencies of 1.98%, 3.42% and 2.34%, respectively, even with very thin 5 pm TiO2 films.

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