4.0 Article

Preparation of Porous PtRuCo Catalyst by One-Step Codeposition and Its Electrocatalytic Performance for Methanol Oxidation

Journal

ELECTROCHEMICAL AND SOLID STATE LETTERS
Volume 12, Issue 7, Pages B112-B115

Publisher

ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3125286

Keywords

catalysis; cobalt alloys; electrochemical impedance spectroscopy; materials preparation; platinum alloys; ruthenium alloys; scanning electron microscopy; transmission electron microscopy; voltammetry (chemical analysis)

Funding

  1. Science and Technology Commission of Shanghai Municipality, China [08JC1402000, 08DZ2270500]

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Porous ternary PtRuCo catalyst supported on a glassy carbon substrate was prepared by one-step electrochemical codeposition using an adsorbed hydrogen gas bubble as a dynamic template. The as-prepared catalyst was characterized by scanning electron microscopy and transmission electron microscopy. Methanol electro-oxidation on the as-prepared catalyst was investigated by cyclic voltammetry, chronoamperometry, and electrochemical impedance spectroscopy, and the results show that porous ternary PtRuCo catalyst has excellent electrocatalytic performance.

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