Journal
ELECTROCHEMICAL AND SOLID STATE LETTERS
Volume 12, Issue 5, Pages A102-A106Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3082038
Keywords
crystal structure; electrochemical electrodes; lithium compounds; secondary cells; solvation
Funding
- Region Picardie
- E. U.
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Li-ion batteries based on active organic electrode materials may present an alternative route to the current battery technology, particularly in terms of recycling cost. Here, we report preliminary data regarding the electrochemical behavior of Li(2)C(6)O(4)Cl(2) obtained by dehydration of the dilithium chloranilate monohydrate, which is formed by spontaneous dehydration of the Li(2)C(6)O(4)Cl(2)center dot similar to 6H(2)O phase. Electrochemically tested vs Li, the anhydrous chloranilate displays a reversible capacity of 200 mAh g(-1) at an average potential of 2.3 V, which slightly decays upon cycling as opposed to Li(2)C(6)O(4)Cl(2)center dot H(2)O. Moreover, thermal recycling of chloranilate phases leads to the LiCl formation, which is a benign salt.
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