4.5 Article

Facile Preparation of α-Zirconium Phosphate/Polyaniline Hybrid Film for Detecting Potassium Ion in a Wide Linear Range

Journal

ELECTROANALYSIS
Volume 26, Issue 2, Pages 416-423

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201300623

Keywords

Cyclic voltammetry; Organic-inorganic hybrid composites; Polyaniline; Potassium; Zirconium phosphate

Funding

  1. National Natural Science Foundation of China [21276173]
  2. Natural Science Foundation of Shanxi Province [2012011020-5]
  3. Shanxi Scholarship Council of China [2013051]
  4. National Youth Foundation of China [201306123]

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A novel -zirconium phosphate/polyaniline (-ZrP/PANI) hybrid film used as K+ ion sensor was fabricated on carbon paper by electrochemical method. Mechanisms of film formation and detection of K+ ions were also proposed. The exfoliated -ZrP was mixed with PANI and deposited on carbon paper. The resultant -ZrP/PANI film exhibited a good current response to K+ ion with different concentrations. It also showed a wide logarithmic linear response in detecting K+ ions in the ranges of 10(-8)-10(-4)M and 10(-4)-10(-2)M, respectively. The results can be attributed to the synergetic effect of -ZrP and PANI.

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