Journal
ELECTROANALYSIS
Volume 23, Issue 1, Pages 129-139Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201000428
Keywords
Voltammetry; Silver solid amalgam composite electrode; Drinking water; River water; Nitro compounds; 2-Nitrofluorene; Picric acid; Metronidazole
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Funding
- Ministry of Education, Youth and Sports of the Czech Republic [LC 06035, MSM 0021620857, RP 14/63]
- Charles University in Prague [89710/2010/B-Ch/PrF, SVV 261204]
- Academy of Sciences of the Czech Republic [IAA400400806]
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Voltammetric behavior of selected biologically active organic nitro compounds, namely 2-nitrofluorene, picric acid (2,4,6-trinitrophenol) and metronidazole, has been investigated using direct current voltammetry (DCV) and differential pulse voltammetry (DPV) at a polished silver solid amalgam composite electrode (p-AgSA-CE). The optimum conditions have been found for their determination in a 1:1 mixture of methanol and aqueous Britton-Robinson buffer of pH 5.0 for 2-nitrofluorene and in the aqueous Britton-Robinson buffer solutions of pH 2.0 and 4.0 for picric acid and metronidazole, respectively, with the limits of quantification (L(Q)s) 4, 0.1 and 2 mu molL(-1) (DCV at p-AgSA-CE) and 3, 1 and 4 mu molL(-1) (DPV at p-AgSA-CE) for 2-nitrofluorene, picric acid and metronidazole, respectively. An attempt to increase the sensitivity using adsorptive stripping voltammetry was not successful for all three test substances. For comparison, the UV-vis spectrophotometric determinations of studied compounds have also been carried out in methanol for 2-nitrofluorene (L-Q approximate to 1 mu molL(-1)) and in deionized water for picric acid (L-Q approximate to 3 mu molL(-1)) and metronidazole (L-Q approximate to 2 mu molL(-1)). Practical applicability of the newly developed voltammetric methods was verified on direct determination of the studied compounds in drinking and river waters with L(Q)s around 10(-6) molL(-1) for all the studied compounds.
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