Journal
ELECTROANALYSIS
Volume 20, Issue 16, Pages 1819-1824Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.200804252
Keywords
nanocomposite; 6-ferrocenylhexanethiol; ascorbic acid; multiwall carbon nanotubes
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Funding
- National Natural Science Foundation of China [20605010]
- Jiangxi Province Natural Science Foundation [0620039]
- Program for Innovative Research Team of Nanchang University
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In this article, a detailed electrochemical study of a novel 6-ferrocenylhexanethiol (HS(CH2)(6)Fc) self-assembled multiwalled carbon nanotubes-Au nanoparticles (MWNTs/Au NPs) composite film was demonstrated. MWNTs/Au NPs were prepared by one-step in situ synthesis using linear polyethyleneimine (PEI) as bifunctionalizing agent. HS(CH2)(6)Fc, which acted as the redox mediator, was self-assembled to MWNTs/Au NPs via Au-S bond. Transmission electron microscopy (TEM), energy-dispersive X-ray analysis (EDX), Fourier transformed infrared absorption spectroscopy (FT-IR), UV-visible absorption spectroscopy, and cyclic voltammetry were used to characterize the properties of the MWNTs/Au NPs/HS(CH2)(6)Fc nanocomposite. The preparation of the nanocomposite was very simple and effectively prevented the leakage of the HS(CH2)(6)Fc mediator during measurements. The electrooxidation of AA could be catalyzed by Fc/Fc(+) couple as a mediator and had a higher electrochemical response due to the unique performance of MWNTs/Au NPs. The nanocomposite modified electrode exhibited excellent catalytic efficiency, high sensitivity, good stability, fast response (within 3 s) and low detection limit toward the oxidation of AA at a lower potential.
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