Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 119, Issue 27, Pages 14834-14842Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.5b00966
Keywords
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Funding
- National High Technology Research and Development Program of China (863 Program) [2011AA050528]
- National Nature Science Foundation of China [51304253]
- Hunan Provincial Natural Science Foundation of China [13JJ6003]
- Fundamental Research Funds for the Central Universities [2012QNZT12]
- Open-End Fund for the Valuable and Precision Instruments of Central South University
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In this study, WO3 nanoplates modified by doping with gadolinium (Gd) were synthesized by a hydrothermal method. The effect of the rare-earth element on the photoelectrochemical (PEC) performance of WO3 one- or two-dimensional (2D) materials was examined. Scanning electron microscopy, transmission electron microscopy, and X-ray diffraction were employed to examine the crystal phase and morphology of the Gd-doped nanoplates thus prepared. Results of UV-vis spectroscopy, valence-band (VB) X-ray photoelectron spectroscopy, and Mott-Schottky analyses indicated that the conduction band and VB potentials of WO3 shifted to negative values. Linear sweep voltammetry results indicated that the photocurrent density increased by 153% after modification by doping with Gd. In addition, the PEC properties of the WO3 nanoplates obtained by the intensity-modulated photocurrent spectrum and incident photon-to-current conversion efficiency measurements indicated that modification by doping with Gd has a scintillating application in improving the PEC conversion properties of WO3-based 2D materials.
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