Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 119, Issue 36, Pages 20931-20939Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.5b05462
Keywords
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Funding
- Office of Naval Research Young Investigator Program [N00014-13-4-0528]
- NSF graduate research fellowship [DGE-0644493]
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The influence of planar organic linkers on thermal boundary conductance across hybrid interfaces has focused on the organic/inorganic interaction energy rather than on vibrational mechanisms in the molecule. As a result, research into interfacial transport at planar organic monolayer junctions has treated molecular systems as thermally ballistic. We show that thermal conductance in phosphonic acid (PA) molecules is ballistic, and the thermal boundary conductance across metal/PA/sapphire interfaces is driven by the same phononic processes as those across metal/sapphire interfaces without PAs, with one exception. We find a more than 40% reduction in conductance across henicosafluorododecyl-phosphonic acid (F21PA) interfaces, independent of metal contact, despite similarities in structure, composition, and terminal group to the variety of other PAs studied. Our results suggest diffusive scattering of thermal vibrations in F21PA, demonstrating a clear path toward modification of interfacial thermal transport based on knowledge of ballistic and diffusive scattering in single monolayer molecular interfacial films.
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