Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 119, Issue 46, Pages 25956-25964Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.5b08018
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Funding
- National Nature Science Foundation of China (NSFC) [51172108]
- Research Fund of State Key Laboratory of Mechanics and Control of Mechanical Structures (Nanjing University of Aeronautics and astronautics) [0514Y01]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Jiangsu Innovation Program for Graduate Education [KYLX_0260]
- Fundamental Research Funds for the Central Universities
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To further improve the photocatalytic H-2 evolution activity, NaNbO3 photocatalyts simultaneously possessing cubic crystal structure and 1D morphology have been successfully synthesized via a modified solvothermal strategy. During the process of synthesis employing ethylene glycol as solvent, a temperature fluctuation during the autoclaving period is proposed to regulate the grain growth without any other additives or calcinations. It is demonstrated that the structure-directing effect of the solvent is enhanced in the condition of the temperature fluctuation, contributing to the formation of 1D nanostructure. Otherwise, the irregular NaNbO3 nanoparticles with severe aggregation resulted. Photocatalytic H-2 evolution activities of samples under ultraviolet light irradiation with 0.5 wt % of Pt cocatalyst indicate that NaNbO3 nanowires expectedly exhibit an enhanced activity of 699 mu mol h(-1) g(-1), approaching twice that of NaNbO3 nanoparticles. The higher photocatalytic activity of NaNbO3 nanowires is attributed to their large specific surface area, high chemical purity, and powerful reduction ability, which have been confirmed by the further characterizations and analysis based on crystal structure, valence state, elemental composition, and energy band structure. The modified solvothermal strategy provides an alternative pathway to regulate the crystal growth, which can effectively integrate the unique morphology with desired crystalline structure toward increasing photocatalytic activity.
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