Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 119, Issue 33, Pages 19011-19021Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.5b05749
Keywords
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Funding
- National Science Foundation SOLAR [1035292]
- MRSEC Program of the NSF [DMR 1121053]
- NSF
- National Science Foundation Graduate Research Fellowship [DGE-1144085]
- Robert A. Welch Foundation [F1599]
- U.S. Army Research Office [W911NF-13-1-0396]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1035292] Funding Source: National Science Foundation
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Ternary blends and energy cascades are gaining popularity as ways to engineer absorption as well as exciton and charge collection in organic solar cells. Here, we use kinetic Monte Carlo simulations to investigate energy cascade designs for improving exciton collection in bilayer solar cells via a Forster energy transfer mechanism. We determine that an interfacial monolayer (C) between the donor and acceptor with a D -> A -> C energy cascade will lead to good exciton collection, allowing for >90% collection, even for energy donor layers up to 75 nm thick. We further examine how roughening the interface, increasing the exciton diffusion length, and using other energy cascade designs affect the enhancement from the energy transfer. We also propose using the inherent charge transfer states at the interfaces as energy acceptors and estimate that the Forster radius could be as large as 3.4 nm, leading to nearly 70% improvement in exciton collection, without the need for a third material.
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