A legacy of Hadean silicate differentiation inferred from Hf isotopes in Eoarchean rocks of the Nuvvuagittuq supracrustal belt (Quebec, Canada)

New Lu-Hf isotopic data for mafic and felsic rocks from the Nuvvuagittuq supracrustal belt (NSB) in northern Quebec (Canada) yield an Eoarchean age of 3864 +/- 70 Ma consistent with both zircon U-Pb and whole-rock Sm-147- Nd-143 chronology, but in disagreement with ca. 4400 Ma ages inferred from the Sm-146-Nd-142 chronometer (O'Neil et al., 2008, 2012). The Lu-Hf result is interpreted as the mean emplacement age of the different autochthonous units of the NSB. An observed alignment of the data along a Lu-Hf scatterchron precludes a Hadean age for the NSB because its isotopic characteristics appear to be controlled by long-term radiogenic ingrowth. Emplacement of the NSB in the Hadean (e.g., 4362(-54)(+35) Ma if the decay constant of Sm-146 of Kinoshita et al. (2012) is used with the O'Neil et al., 2008 data) should instead have caused age differences of hundreds of millions of years to manifest as strong deviations from the Lu-Hf scatterchron. Combined Lu-Hf and Sm-Nd data on the same NSB amphibolite samples (Ca-poor cummingtonite- and hornblende-bearing) define a mixing hyperbola at ca. 3800 Ma with end-member compositions representative of the compositional groups identified for these lithologies (O'Neil et al., 2011). Anomalously low Nd-142/Nd-144 values relative to Bulk Silicate Earth are endemic to a group of rocks in the NSB termed low-TiO2 amphibolites; this is attributable to an ancient multi-stage history of their mantle source. Modeling shows that the Nd-142/Nd-144 deficits could have developed in response to a re-fertilization episode within a previously fractionated mantle domain at 4510 Ma. (C) 2012 Elsevier B.V. All rights reserved.