Chlorine isotope composition of volcanic gases and rocks at Mount Etna (Italy) and inferences on the local mantle source

We present the first chlorine isotope compositional data for gases and lavas from Mount Etna (Italy), and to our knowledge, of active Mediterranean volcanism. We investigated lavas erupted and gases discharged during 2008-2011 from a high-temperature fumarole (HT; >300 degrees C) and plume gases from both North East and Central Craters. Most of the samples vary in a narrow range of chlorine isotope composition (delta Cl-37 values approximate to 0 +/- 0.7 parts per thousand) with gases partially overlapping with rocks. Only HT gases sampled in 2009 have been clearly affected by secondary processes (delta Cl-37 values>15.9 parts per thousand), resulting in partial removal of chlorine and isotopic fractionation producing a Cl-37 enrichment in the residual gaseous HCl. These secondary processes also affect, although to a lesser extent, plume gases from North East Crater (NEC). Although post-magmatic processes are able to modify the chlorine isotope composition, delta Cl-37 values are not affected by magma degassing for residual fractions >= 0.3 in the melt, or any effect is within our data variability. Finally, delta Cl-37 values and Cl/K ratios of magmatic chlorine constrain the Etnean source to be compatible with depleted mantle (DMM) contaminated by altered oceanic crust (AOC), in agreement with indications from more common isotopic tracers of mantle processes. (c) 2013 Elsevier B.V. All rights reserved.