Journal
EARTH AND PLANETARY SCIENCE LETTERS
Volume 311, Issue 3-4, Pages 225-229Publisher
ELSEVIER
DOI: 10.1016/j.epsl.2011.09.032
Keywords
pressure-induced phase transition; postperovskite; super-Earth; 10 solar giants; first principles
Categories
Funding
- NSF [EAR-1047629]
- Directorate For Geosciences
- Division Of Earth Sciences [1019853] Funding Source: National Science Foundation
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The fate of MgSiO3 post-perovskite under TPa pressures is key information for understanding and modeling interiors of super-Earths-type exoplanets and solar giants' cores. Here, we report a dissociation of MgSiO3 post-perovskite into CsCl-type MgO and P2(1)/c-type MgSi2O5 at similar to 0.9 TPa obtained by first principles calculations. P2(1)/c-type MgSi2O5 should dissociate further into CsCl-type MgO and Fe2P-type SiO2 at similar to 2.1 TPa. The first dissociation should occur in all solar giants and heavy super-Earths, while the second one should occur only in Jupiter and larger exoplanets. Both dissociations are endothermic and have large negative Clapeyron slopes. If the first dissociation should occur in the middle of a silicate mantle, it could promote mantle layering. We provide essential thermodynamic properties of P2(1)/c-type MgSi2O5 for modeling interiors of super-Earths. (C) 2011 Elsevier B.V. All rights reserved.
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