Journal
EARTH AND PLANETARY SCIENCE LETTERS
Volume 288, Issue 3-4, Pages 534-538Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.epsl.2009.10.015
Keywords
hcp-Fe; inner core; elasticity; seismic anisotropy
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Funding
- Natural Environment Research Council [NE/C519662/1] Funding Source: researchfish
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Ab initio finite temperature molecular dynamics simulations have been used to calculate the elastic constants of hexagonal-close-packed (hcp) Fe as a function of temperature at similar to 300 GPa. The longitudinal modulus c(1)1 decreases with temperature, in stark contrast to previous calculations, but in agreement with experimental observations on other transition metals at ambient pressures. c(33) and c(44) also decrease with temperature, while c(12) and c(23) slightly increase. When these moduli are used to calculate P-wave velocities through the crystal, the sense of the anisotropy is such that V(P) is fastest along the c-axis up to 5000 K: however, by 5500 K the anisotropy reverses with V(P) becoming faster in the a-b plane. This suggests that, for an inner core dominated by crystals of hcp-Fe aligned with the c-axis in the polar direction, the observed isotropic outer-inner core could result from the hcp-Fe being at a temperature close to melting where the axial wave velocities parallel and perpendicular to the c-axis become similar, while at greater depths in the inner-inner core, where iron is further from melting, stronger anisotropy is achieved with the faster P-wave velocities parallel to the polar axis. No other mechanisms, such as changes in composition or crystal alignment, are therefore required to account for the observed change in seismic anisotropy of the Earth's inner core with depth. (C) 2009 Elsevier B.V. All rights reserved.
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