Isotopic fractionation of zinc in tektites

Tektites are terrestrial natural glasses produced during a hypervelocity impact of an extraterrestrial projectile onto the Earth's surface. The similarity between the chemical and isotopic compositions of tektites and terrestrial upper continental crust implies that the tektites formed by fusion of such target rock. Tektites are among the driest rocks on Earth. Although volatilization at high temperature may have caused this extreme dryness, the exact mechanism of the water loss and the behavior of other volatile species during tektite formation are still debated. Volatilization can fractionate isotopes, therefore, comparing the isotope composition of volatile elements in tektites with that of their source rocks may help to understand the physical conditions during tektite formation. For this study, we have measured the Zn isotopic composition of 20 tektites from four different strewn fields. Almost all samples are enriched in heavy isotopes of Zn compared to the upper continental crust. On average, the different groups of tektites are isotopically distinct (listed from the isotopically lightest to the heaviest): Muong-Nong type indochinites (delta Zn-66/64=0.61 +/- 0.30 parts per thousand); North American bediasites (delta Zn-66/64=1.61 +/- 0.49 parts per thousand); Ivory Coast tektites (delta Zn-66/64=1.66 +/- 0.18 parts per thousand); the Australasian tektites (others than the Muong Nong-type indochinites) (delta Zn-66/64=1.84 +/- 0.42 parts per thousand); and Central European moldavites (delta Zn-66/64=2.04 +/- 0.19 parts per thousand). These results are contrasted with a narrow range of delta Zn-66/64=0-0.7 parts per thousand for a diverse spectrum of upper continental crust materials. The elemental abundance of Zn is negatively correlated with delta Zn-66/64, which may reflect that isotopic fractionation occurred by evaporation during the heating event upon tektite formation. Simple Rayleigh distillation predicts isotopic fractionations much larger than what is actually observed, therefore, such a model cannot account for the observed Zn isotope fractionation in tektites. We have developed a more realistic model of evaporation of Zn from a molten sphere: during its hypervelocity trajectory, the molten surface of the tektite will be entrained by viscous coupling with air that will then induce a velocity field inside the molten sphere. This velocity field induces significant radial chemical mixing within the tektite that accelerates the evaporation process. Our model, albeit parameter dependent, shows that both the isotopic composition and the chemical abundances measured in tektites can be produced by evaporation in a diffusion-limited regime. (C) 2008 Elsevier B.V. All rights reserved.