Journal
DYES AND PIGMENTS
Volume 99, Issue 3, Pages 871-877Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2013.07.033
Keywords
Hydrogen sulfide; Fluorescent probe; Ratiometric; Excited-state intramolecular proton transfer; Benzothiazole; Nucleophilicity
Funding
- National Natural Science Foundation of China [21275117, 21175106]
- Science & Technology Department [2012JM2004]
- Education Department of Shaanxi Province of China [12JK0518]
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A ratiometric fluorescent probe for hydrogen sulfide (H2S) has been developed based on modulation of the excited-state intramolecular proton transfer (ESIPT) process of 2-(2'-hydroxy-3'-methoxyphenyl) benzothiazole (HMBT). The probe was prepared by coupling HMBT with 3,3'-dithiodipropionic acid, and it only displays enol-like fluorescence emission at 374 nm. However, upon introducing H2S in neutral solution, the protecting groups of the probe was removed via the tandem nucleophilic substitution/cyclization reaction, thereby retrieving the ESIPT process of HMBT, which resulted in a decrease of the emission band at 374 nm along with a concomitant increase of a new fluorescence peak at 478 nm. The fluorescent intensity ratio at 478 and 374 nm (I-478/I-374) increases linearly with H2S concentration in the range 0.5-10 mu M. The proposed probe shows excellent selectivity toward H2S over other common anions and biothiols. (C) 2013 Elsevier Ltd. All rights reserved.
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