Journal
DYES AND PIGMENTS
Volume 92, Issue 2, Pages 838-846Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2011.05.006
Keywords
Photomodulation; Gated-photochromism; Diarylethene; Thiazole; Kinetic modelling; Acid catalysis
Funding
- Grants-in-Aid for Scientific Research [11J08784] Funding Source: KAKEN
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The acid-gated photochromism and the photomodulation of fluorescence and proton affinity of a novel dimethylaminophenyl thiazole diarylethene in MeCN were investigated from a kinetic point of view. Photomodulation of the proton affinities has been estimated from acid titrations and numerical modelling of the acid induced T-photochromism. The basicities of the thiazole and dimethylamino protonation sites are different by only one pK unit. Upon ring- closure, their relative proton affinities are reversed. Our investigations underline the role of the thiazole protonation in the carbon-carbon bond weakening of the closed form and validate the role of the proton as catalyst in the gated T-photochromism. (C) 2011 Elsevier Ltd. All rights reserved.
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