Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 300, Issue -, Pages 22-26Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2014.12.008
Keywords
Photochemistry; Photosensitive materials; Photochromism; Photoacid
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Funding
- Air Force Office of Scientific Research [FP048956]
- National Science Foundation [DMR 1342940]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1342940] Funding Source: National Science Foundation
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Photochromism based on reversible proton transfer between metastable-state photoacids and acidochromic dyes is studied. Metastable-state photoacids reversibly produce a large proton concentration under moderate irradiation, protonate the acidochromic dyes and induce color change. This mechanism is different from that of conventional photochromic materials based on photoinduced structural change. The color change and the stimulating wavelength can be controlled by choosing different acidochromic dyes and photoacids. Reversible changes of various colors under sunshine or visible lights of different wavelengths were demonstrated in both solutions and polymer matrix. (C) 2014 Elsevier B.V. All rights reserved.
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