Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 297, Issue -, Pages 31-38Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2014.09.013
Keywords
Naphthalimide derivative; Internal charge transfer (ICT); Photoinduced electron transfer (PET); Selective pH sensing in 100% aqueous media; AND,XOR,XNOR, and INH logic gates; Magnitude digital comparator and halfadder
Categories
Funding
- Deanship of Scientific Research (DSR)
- King Abdulaziz University [5-130-35-HiG]
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The design, synthesis, and sensor activity of a novel highly water-soluble 9,10-dihydro-7H-imidazo[1,2-b] benz[d,e]isoqionolin-7-one derivative are reported. The changes in the photophysical properties of the compound as a function of pH were investigated in 100% aqueous medium. Novel compound manifests ratiometric off-on-off' pH sensor activity. Due to the two different off-states, it is able to execute the logical functions AND and XOR as well as INH and XNOR and as such, to act as a half-adder and a magnitude digital comparator, respectively. The synthesized compound shows excellent selectivity toward protons over the representative metal ions in ammonia/ammonium chloride buffer (pH 10) and HEPES (pH 7.3) solutions. The high water solubility and excellent pH selectivity and sensitivity of the probe may be beneficially for monitoring pH variations in complex samples. (C) 2014 Elsevier B.V. All rights reserved.
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