Journal
DIAMOND AND RELATED MATERIALS
Volume 17, Issue 3, Pages 318-324Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.diamond.2007.12.043
Keywords
carbon nanotubes; MWNT; Raman spectroscopy; catalytic processes; chemical vapor deposition
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We performed experiments on the synthesis of carbon nanotubes (CNTs) by iron-catalyzed chemical vapor deposition (CVD) in C2H6+H-2 atmosphere. We varied flow-rates of reactant gases (ethane: 30-120 seem, hydrogen: 0-120 seem), as well as their ratio, in order to study the evolution of the growth kinetics. We used scanning electron microscopy, high-resolution transmission electron microscopy and Raman spectroscopy to investigate the morphologies, dimensions and crystalline structure of the samples. Our results demonstrate the crucial role played by H-2 in the enhancement of C diffusion-rate and in the consequent development of ordered and smooth graphene layers. A faster growth-rate is achieved by the increase of C2H6 flow-rate. However, if H-2 flow-rate is not adequately enhanced, the improvement is only apparent. The excess of C supplied gives rise to deposition of amorphous carbon onto the CNT walls, and to the co-production of different nanostructures. A substantial agreement is found with results reported for CVD growth of CNTs by the use of different catalysts, reactants and gas-flowing setups. (C) 2008 Elsevier B.V. All rights reserved.
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