Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 798, Issue -, Pages 209-213Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2015.05.009
Keywords
BODIPY; Carborane; BNCT; Fluorescence; BBB model
Categories
Funding
- National Institutes of Health [R01 CA179902]
- National Science Foundation [1362641]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1362641] Funding Source: National Science Foundation
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A series of four BODIPYs containing one or two ortho- or para-carborane clusters were synthesized using palladium(0)-catalyzed Suzuki cross-coupling or nucleophilic substitution reactions, at the 2,6- or the 8-positions of halogenated boron dipyrromethenes (BODIPYs). The spectroscopic, structural (including one X-ray) and in vitro BBB permeability of the BODIPYs using hCMEC/D3 brain endothelial cells were investigated. (C) 2015 Elsevier B.V. All rights reserved.
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