Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 24, Pages 12588-12593Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01666
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Funding
- National Natural Science Foundation of China [21272117, 21502097]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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2-(Alkylamino)benzonitriles were synthesized via a rhodium-catalyzed cyanation on the aryl C-H bond and subsequent denitrosation of N-nitrosoarylamines using a removable nitroso as the directing group, in which N-cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS) was used as the CN source. Various substituents on the aryl ring and amino group of N-nitrosoarylamines tolerated the reaction, and the corresponding products were achieved in moderate to good yields.
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