Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 7, Pages 3695-3700Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00142
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Funding
- Indian Institute of Technology Madras [CHY/11-12/569/NFSC/ANBA]
- Board of Research in Nuclear Sciences (BENS) through DAE Young Scientist Award [2012/20/37C/14/BRNS]
- Council of Scientific & Industrial Research (CSIR)
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An efficient and general rhodium(III) catalyzed C2-selective cyanation of indoles and pyrroles was accomplished employing easily accessible and environmentally friendly cyanating reagent, NCTS. This methodology tolerates various functional groups, uses readily removable directing groups and allows the synthesis of various 2-cyanoindoles and pyrroles in good to excellent yield.
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