Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 11, Pages 5859-5869Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00891
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Funding
- National Research Foundation of Korea (NRF) - Korea government (MSIP) [2014001403]
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A synthetic route to a wide range of 2-alkoxyaryl-2-aryl enamines is developed from Rh-catalyzed alkoxyarylation of N-sulfonyl-4-aryl-1,2,3-triazoles with aryl ethers via the elimination of nitrogen molecule. In addition, 2-alkoxyaryl-2-aryl enamines are prepared via tandem Cu-catalyzed cycloaddition and Rh-catalyzed alkoxyarylation starting from apes, N-sulfonyl azides, and aryl ethers in one-pot.
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