Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 1, Pages 265-270Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01995
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Funding
- National Natural Science Foundation of China [21421004, 21172069, 21372072, 21190033]
- NCET [NCET-13-0798]
- Basic Research Program of the Shanghai Committee of Sci. Tech. [13M1400802]
- Fundamental Research Funds for the Central Universities
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A multicomponent cascade reaction is described that provides concise access to the trifluoroethyl isoquinolines using a Rh(III)-Cu(II) bimetallic system and readily available Togni's reagent. The system tolerates various vinyl azides and internal alkynes. Experimental results suggest that Togni's reagent might act as a CF3 radical supplier.
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