Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 16, Pages 8361-8366Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00940
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- Chinese Academy of Science
- NSFC
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Cp*Rh(III) complexes have been applied as efficient catalysts for the C-H activation and trifluoromethylthiolation of indoles functionalized with a heterocycle. With N-trifluoromethylthiosaccharin being an electrophilic SCF3 reagent, this C-S coupling occurred selectively at the 2-position with good functional group tolerance.
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