Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 4, Pages 2319-2332Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo502882y
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The three-component reaction between a nitrobenzene, an aldehyde, and a dienophile in the presence of iron powder as a reductant and montmorillonite K10 as a catalyst in aqueous citric acid delivers the products of an aza-DielsAlder (Povarov) reaction with high endo-selectivity and yields up to 99%.
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