Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 13, Pages 6529-6536Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00672
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- University of Wollongong
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We report a highly efficient ring-opening reaction of vinylcydopropanes by boronic acids in water, using palladium nanoparticles formed from Pd(OAc)(2) under ligandless conditions. Unsubstituted vinylcydopropanes provide linear addition products with high selectivity, while a switch in regioselectivity to branched products is observed for aryl-substituted vinylcydopropanes.
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