Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 22, Pages 11441-11446Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b02084
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Funding
- Shanghai Municipal Education Commission [14ZZ159]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars
- State Education Ministry (SRF for ROCS, SEM)
- Special Scientific Foundation for Outstanding Young Teachers in Shanghai Higher Education Institutions [ZZGJD13020]
- Start-up Funding of Shanghai University of Engineering Science [2013-24]
- students Innovation Program in Shanghai University of Engineering Science [14KY0413]
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N-heterocyclic carbene borane (NHC-borane) baled on a triazole core is demonstrated for the first time to be efficient for reduction of a variety of tert-butanesulfinyl ketimines. Up to 95% yield and up to >99% diastereomeric excess were achieved. NHC-borane exhibited excellent activities that are more efficient than or comparable to commonly used reductive reagents such as NaBH4, NaBH3CN, L-selectride, Ru catalyst, or BH3-THF.
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