Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 11, Pages 5900-5905Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00232
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Funding
- Ministry of Science and Technology of China [2011CB808600]
- National Science Foundation of China [21272237]
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The enantioselective N-heterocyclic carbene-catalyzed [4 + 2] cyclocondensation of alpha-chloroaldehydes and trifluoromethyl N-Boc azadienes was developed, giving the corresponding 3,4-disubstituted-6-trifluoromethyldihydropyridin-2(1H)-ones in good yields with exclusive cis-selectivities and excellent enantioselectivities.
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